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TECHNICAL INFORMATION

Technical Information

Understand what Cathodic Protection is

What Is Cathodic Protection?

Corrosion of boat parts takes place because of galvanic and/or electrolytic corrosion which are both complex sciences, but put more simply: any metal parts left in water (especially salt water) will be subjected to some form of electro-chemical reaction, where one metal is eroded away at the expense of others. In a marine context, the extent of the corrosion depends on the salinity of the water, the electrical potential between and the dissimilarity of the metals and the amount of electrical activity involved in the vicinity.

To stop the expensive parts of a boat, ship or structure being corroded away, a more reactive but inexpensive lump of metal is positioned close to and in sight of the metal to be protected, and electrically bonded to it. This cheaper and more reactive metal will be eaten away instead of the hull, shaft or rudder you are trying to protect.

This form of protection is called “cathodic protection” and uses a “sacrificial anode” to protect your expensive parts. In the USA, they are referred to as “zincs”.

Metal Types and Their Use

There are three types of metal alloy used. In each, the composition is critical to their correct operation, and all good quality manufacturers use the alloys shown below. Our suppliers use these alloys and have strict quality controls in place to ensure you will always get the best corrosion protection. The metal alloy compositions were formulated after many years of research by the U.S. military and have been internationally adopted by the leading foundries and accepted as best practice.

Zinc alloy is used in salt water environments. The alloy allows the potential to remain adequate in a wide range of temperatures up to 50 degree C, and in varying salinities.

Aluminium alloy is used in brackish estuarine waters, but can be used just as effectively in salt water.

Magnesium alloy is only ever used in the fresh waters of lakes, rivers and canals.
Zinc Alloy to U.S. Military Specification 18001K and ASTM-418-95 Type I
Composition

Iron

Fe

0.005% max.

Cadmium

Cd

0.025-0.07%

Copper

Cu

0.005% max.

Aluminium

Al

0.10-0.50%

Lead

Pb

0.0006% max.

Others (total)

0.10% max

Zinc

Zn

Remainder

Potential

ECP ref:Ag/AgCl

1.05V

Capacity

Amp.hr/Kg

780

Aluminium Alloy to U.S. Military Specification 24779B
Composition

Iron

Fe

0.09% max.

Silicon

Si

0.080- 0.20%

Copper

Cu

0.004% max.

Zinc

Zn

4.0-6.5%

Indium

In

0.014- 0.020%

Titanium

Ti

N/A

Gallium

Ga

N/A

Mercury

Hg

0.001% max.

Nickel

Ni

780

Others (total)

0.025% max.

Aluminium

Al

Remainder

Potential

ECP ref:Ag/AgCl

-1.05V

Capacity

Amp.hr/Kg

2535

Magnesium Alloy to U.S. Military Specification A21412
Composition

Iron

Fe

0.005% max.

Cadmium

Cd

0.025-0.07%

Copper

Cu

0.005% max.

Aluminium

Al

0.10-0.50%

Lead

Pb

0.0006% max.

Others (total)

0.10% max

Zinc

Zn

Remainder

Potential

ECP ref:Ag/AgCl

1.05V

Capacity

Amp.hr/Kg

780

Iron

Fe

0.09% max.

Silicon

Si

0.080- 0.20%

Copper

Cu

0.004% max.

Zinc

Zn

4.0-6.5%

Indium

In

0.014- 0.020%

Titanium

Ti

N/A

Gallium

Ga

N/A

Mercury

Hg

0.001% max.

Nickel

Ni

780

Others (total)

0.025% max.

Aluminium

Al

Remainder

Potential

ECP ref:Ag/AgCl

-1.05V

Capacity

Amp.hr/Kg

2535

Copper

Cu

0.08% max.

Aluminium

Al

5.3- 6.7%

Silicon

Si

0.3% max.

Iron

Fe

0.005% max.

Manganese

Mn

0.25% min.

Nickel

Ni

0.003% max.

Zinc

Zn

2.3 – 3.5%

Lead

Pb

0.03% max.

Magnesium

Mg

Remainder

Potential

ECP ref:Ag/AgCl

-1.55V

Capacity

Amp.hr/Kg

1105

Where Do You Use Your Boat?

They say nothing is simple in life, and so it is with choosing your anodes. If you use your boat constantly in one aquatic environment, it is simple; zinc for salt, aluminium for brackish estuarine waters and magnesium for the fresh waters of lakes and canals.

The problems start when, like most people, you move between the environs. If you use magnesium anodes in brackish or salt waters, they will be eaten away very quickly. Conversely, if you use zinc in freshwater or low salt estuaries, they will oxidise and become blinded. Aluminium will also become ineffective in a freshwater lake.

If you are going to transfer your boat to a different water type for more than a few weeks, it is advisable to change your anodes for the correct type. If you are daily moving between the zones, just choose your anodes for the major usage, and then keep a constant check on them to make sure they are being corroded and not being covered in a white crust.

Types of Anode Available

After you have chosen the best metal for your particular boat’s use, the next decision is what needs protecting and how.

The chances are that you are replacing anodes that have already been fitted and, therefore, it is just a matter of replacing like with like.

All anodes should be positioned as close to, and in line of sight of the part they are designed to protect. They must be electrically bonded to the protected part with 4mm2 multi-stranded cable.

A] Rudders – various sizes and weights of round disc anodes, some of which are through-bolting pairs available to mount to the rudder below the waterline.

B] Trim tabs (or flaps) – The same round disc anodes are usually mounted to the trim tabs.

C] Propellers – To protect the propeller shaft and nut, a propeller nut end anode is used. This is fixed to the brass propeller nut and stopped rotating by an internal hexagonal mating form or a taper and keyway.

D] Propeller shafts – there are two main types, namely eggs and collars. They are clamped in position on the shaft. Due to their small surface area compared to the exposed shaft, they have only a limited effect.

E] Hulls – This section has the most variants in design, fixing styles and weights. They can be welded on with extended steel straps or, in most cases, bolted in place. On steel or aluminium hulls, there will be many anodes fitted to stop corrosion. In GRP and wooden hulls there will be far fewer and they will be mainly protecting metal fixings. This type of anode has a different style depending on the historic favourite of the boat builder's region or industry. They all carry out the same function, and it is only the attachment which varies.

F] Bow thrusters – The propeller ends of the bow thrusters have specialist small anodes fitted.

G] Engines – Engine blocks are protected by pencil anodes held in brass holders positioned in various parts of the water channel of the engine block. It is important that these are checked and replaced regularly, to fully protect the engine.

H] Engine outdrives – Whatever the style of power output of the engine, whether it be saildrives, sterndrives or separate outboards, they will all be fitted with multiple specialist anodes to protect the parts and the lifting rams. 

Checking and Maintenance

It is important that the anodes fitted to your ship, yacht or structure are checked at regular intervals. This is normally carried out at the same time as the routine maintenance and should ideally be every 6 months, but definitely no longer than 12 months.

The condition of the anodes at the time of inspection is an important indicator of their suitability for your application.

  • If the anodes appear to be a dull dark grey colour and be corroded away evenly with more than 30% of their volume left, it shows a good working anode in need of timely replacement.
  • If the anode is still the same or similar external size as when fitted, the electrical bonding, positioning or metal alloy type should be questioned.
  • If the anode is severely corroded, it should raise concerns about the service interval, or the amount of sacrificial material fitted.
  • Finally, if the surface of the anode is pitted and covered with a large amount of white caking, it probably means your anodes have become blinded by oxide, due to incorrect metal alloy and are no longer working. 
If you have any questions about the suitability of your anodes, talk to our friendly sales team, who will try and answer your concerns or at least know a man who can. Phone 01794 523 007 or email anodes@anodesupplies.com to talk to one member of our team.
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